Publications

(225-8) P. Sondhi, T. M. Adeniji, A. V. Demchenko, and K. J. Stine. Sensitive and specific electrochemical recognition of glycoprotein biomarkers using lectin-modified hierarchically nanostructured gold electrode. Submitted in July 2023
PMID: IP (2R01-33)

(224) N. P. Forsythe, E. R. Mize, G. A. Kashiwagi, and A. V. Demchenko. Expedient synthesis of superarmed glycosyl donors via oxidative thioglycosidation of glycals. Synthesis, 2023, in press (Special issue) PMID: IP (2R01-32, 3NSF-30)
https://doi.org/10.1055/a-2183-0175

(223) Y. Singh, S. Escopy, M. D. Bandara, K. J. Stine, and A. V. Demchenko. Chemical synthesis of human milk oligosaccharides: para-lacto-N-hexaose and para-lacto-N-neohexaose. Chem. Eur. J., 2023, 29, e202302288 PMID: 37639512 (2R01-31)
http://doi.org/10.1002/chem.202302288

(222) A. Romerio, A. R. Franco, M. Shadrick, M. M. Shaik, V. Artusa, A. Italia, F. Lami, A. V. Demchenko, and F. Peri. Overcoming challenges in chemical glycosylation to achieve innovative vaccine adjuvants possessing enhanced TLR4 activity. ACS Omega, 2023, 8, 36412-36417
PMID: 37810727
https://doi.org/10.1021/acsomega.3c05363

(221) A. Dent, S. Escopy, and A. V. Demchenko. Cooperatively catalyzed activation of thioglycosides that bypasses intermediacy of glycosyl halides. Chem. Eur. J., 2023, 29, e202300873 PMID: 37154481 (2R01-30, 3NSF-29)
http://dx.doi.org/10.1002/chem.202300873

(220) N. Forsythe, L. Liu, G. A. Kashiwagi, and A. V. Demchenko. Activation of thioglycosides under mild alkylation conditions. Carbohydr. Res., 2023, 531, 108872 (Special issue) PMID: 37348387 (2R01-29)
https://doi.org/10.1016/j.carres.2023.108872

(219) P. Sondhi, D. Neupane, J. K. Bhattarai, H. Ali, A. V. Demchenko, and K. J. Stine. Versatile technique to produce a hierarchical design in nanoporous gold. J. Vis. Exp., 2023, 192, e65065 PMID: 36847406 (2R01-28)
http://doi.org/10.3791/65065

(218) P. Sondhi, D. Lingden, J. K. Bhattarai, A. V. Demchenko, and K. J. Stine. Applications of nanoporous gold in therapy, drug delivery, and diagnostics. Metals, 2023, 13, 78 PMID: IP (2R01-27)
https://doi.org/10.3390/met13010078

(224) F. Pooladian, S. Escopy, and A. V. Demchenko. Activation of thioglycosides with copper(II) bromide. Molecules, 2022, 27, 7354 (Special issue) PMID: 36364179 (2R01-26) https://doi.org/10.3390/molecules27217354

(223) P. Sondhi, D. Neupane, J. K. Bhattarai, A. V. Demchenko, and K. J. Stine. Facile fabrication of hierarchically nanostructured gold electrode for bio-electrochemical applications. J. Electroanal. Chem., 2022, 116865 PMID: 36405880 (2R01-25) https://doi.org/10.1016/j.jelechem.2022.116865

(222) M. Shadrick, K. J. Stine, and A. V. Demchenko. Expanding the scope of stereoselective α-galactosylation using glycosyl chlorides. Bioorg. Med. Chem., 2022, 73, 117031 (Special issue) PMID: 36202065 (2R01-24) https://doi.org/10.1016/j.bmc.2022.117031

(221) M. Novakova, A. Das, C. Alex, and A. V. Demchenko. Synthesis and glycosidation of building blocks of D-altrosamine. Front. Chem., 2022, 10, 945779 PMID: 36226114 (2R01-23) https://doi.org/10.3389/fchem.2022.945779

(220) S. A. Geringer, G. A. Kashiwagi, and A. V. Demchenko. Broadening the scope of the reverse orthogonal strategy for oligosaccharide synthesis. J. Org. Chem., 2022, 87, 9887-9895 PMID: 35862424 (2R01-22) https://doi.org/10.1021/acs.joc.2c00905

(219)   Y. Singh, S. Escopy, K. J. Stine, and A. V. Demchenko.  Chemical synthesis of human milk oligosaccharides: two common linear hexasaccharide core structures.  In preparation. 

(218)   A. Dent, A. Escopy, and A. V. Demchenko.  Cooperatively-catalyzed activation of thioglycosides that bypasses intermediacy of glycosyl halides. In preparation.

(217, #13 @SLU)     F. Pooladian, S. Escopy, and A. V. Demchenko. Activation of Thioglycosides with Copper(II) Bromide. Molecules, 2022, in press. (Special issue)  PMID:  (2R01-)

(216, #12 @SLU)     P. Sondhi, D. Neupane, J. K. Bhattarai, A. V. Demchenko, and K. J. Stine.  Facile fabrication of hierarchically nanostructured gold electrode for bio-electrochemical applications.  Submitted to J. Electroanal. Chem., August 2022  PMID:  (2R01-)

(215, #11 @SLU)     M. Shadrick, K. J. Stine, and A. V. Demchenko.  Expanding the Scope of Stereoselective α-Galactosylation Using Galactosyl Chlorides. Submitted to Bioorg. Med. Chem., 2022, 117031 (Special issue)  PMID:  (2R01-24)  https://doi.org/10.1016/j.bmc.2022.117031

(214, #10 @SLU)     M. Novakova, A. Das, C. Alex, and A. V. Demchenko.  Synthesis and glycosidation of building blocks of D-altrosamine.  Front. Chem., 2022, 10, 945779 PMID:  (2R01-23) https://doi.org/10.3389/fchem.2022.945779

(213, #9 @SLU)       S. A. Geringer, G. A. Kashiwagi, and A. V. Demchenko.  Broadening the scope of the reverse orthogonal strategy for oligosaccharide synthesis.  J. Org. Chem., 2022, 87, 9887-9895 PMID: 35862424 (2R01-22) https://doi.org/10.1021/acs.joc.2c00905

(212, #8@SLU)        Y. Singh, S. A. Geringer, and A. V. Demchenko.  Synthesis and glycosidation of anomeric halides: evolution from early studies to modern methods of the 21st century.  Chem. Rev., 2022, 122, 11701-11758  PMID: 35675037 (2R01-21, 3NSF-28) https://doi.org/10.1021/acs.chemrev.2c00029

(211, #7@SLU)        S. Escopy, Y. Singh, K. J. Stine, and A. V. Demchenko.  HPLC-based automated synthesis of glycans in solution.  Chem. Eur. J., 2022, 28, e202201180 PMID: 35513346 (2R01-20) http://doi.org/10.1002/chem.202201180

(210, #6@SLU)        O. Slater, K. B. Dhami, G. Shrestha, M. Kontoyianni, M. R. Nichols, and A. V. Demchenko.  Development of a simple and effective Lipid-A antagonist based on computational prediction.  ACS Infect. Dis, 2022, 8, 1171-1178 (Special issue) PMID: 35612826 (2R01-19) https://doi.org/10.1021/acsinfecdis.2c00125

(209, #5@SLU)        G. Shrestha, M. Panza, Y. Singh, K. J. Stine, and A. V. Demchenko.  N-Alkylated analogues of indolylthio glycosides as glycosyl donors with enhanced activation profile.  Eur. J. Org. Chem., 2022, 2022, e202200300 PMID: (3NSF-27, 2R01-18) http://doi.org/10.1002/ejoc.202200300

(208, #4@SLU)        S. Escopy and A. V. Demchenko.  Transition-metal-promoted activation of thioglycosides and related compounds.  Chem. Eur. J., 2022, 28, e202103747 PMID: 34935219 (3NSF-26) http://doi.org/10.1002/chem.202103747

(207, #3@SLU)        C. Alex and A. V. Demchenko.  Direct synthesis of glycans containing challenging ManNAcA residues.  J. Org. Chem., 2022, 87, 271-280  PMID: 34928148 (3NSF-25) https://doi.org/10.1021/acs.joc.1c02351

(206, #2@SLU)        G. Shrestha, G. A. Kashiwagi, K. J. Stine, and A. V. Demchenko.  Streamlined access to carbohydrate building blocks: methyl 2,4,6-tri-O-benzyl-α-D-glucopyranoside. Carbohydr. Res., 2022, 511, 108482  PMID: 34856429 (2R01-17)  https://doi.org/10.1016/j.carres.2021.108482

(205 #1@SLU) C. Alex and A. V. Demchenko.  Recent advances in stereocontrolled mannosylation: focus on glycans comprising acidic and/or amino sugars. The Chemical Record, 2021, Chem. Rec., 2021, 21, 3278-3294 PMID: 33885577 (3NSF-24) https://doi.org/10.1002/tcr.202100201

(204)📖 M. Shadrick, M. Panza, Vijaya Ganesh N., S. G. Pistorio, K. J. Stine, and A. V. Demchenko.  HPLC-based automated oligosaccharide synthesis.  In Comprehensive Glycoscience, 2nd Edition, J.J. Barchi EIC, Elsevier, 2021, vol 2, 623-636 PMID:  IP   (2R01-16, U01-28)

Also included in the Reference Module in Chemistry, Molecular Sciences and Chemical Engineering, 2020 https://doi.org/10.1016/B978-0-12-819475-1.00006-7

(203)H. B. Steber, Y. Singh, and A. V. Demchenko.  Bismuth(III) triflate as a novel and efficient activator for glycosyl halides.  Org. Biomol. Chem., 2021, 19, 3220-3233 PMID: 33885577 (2R01-15, 3NSF-23) https://doi.org/10.1039/D1OB00093D

(202) C. Alex, S. Visansirikul, and A. V. Demchenko.  A versatile approach to the synthesis of glycans containing mannuronic acid residues.  Org. Biomol. Chem., 2021, 19, 2731-2743 PMID: 33687051 (3NSF-22) https://doi.org/10.1039/D1OB00188D

(201) S. Escopy, Y. Singh, and A. V. Demchenko.  Palladium(II)-assisted activation of thioglycosides.  Org. Biomol. Chem., 2021, 19, 2044-2054 PMID: 33599667 (2R01-14, 3NSF-21) https://doi.org/10.1039/D1OB00004G

(200) J. K. Bhattarai, D. Neupane, B. Nepal, A. V. Demchenko, and K. J. Stine.  Nanoporous gold monolith for high loading of unmodified doxorubicin and sustained co-release of Doxorubicin-Rapamycin.  Nanomaterials, 2021, 11, 208 PMID: 33467416 (2R01-13) https://doi.org/10.3390/nano11010208

(199)📖 M. Panza, M. P. Mannino, A. V. Demchenko, and K. N. Baryal.  Synthesis and characterization of 4-methylphenyl 2,3,4,6-tetra-O-benzoyl-1-thio-β-D-galactopyranoside.  In “Carbohydrate Chemistry: Proven Synthetic Methods,” Volume 5, P. Kosma, T. M. Wrodnigg, A. Stutz Eds., CRC Press, 2021, 163-172 (3NSF-20, U01-27 https://doi.org/10.1201/9781351256087

(198) S. Escopy, Y. Singh, K. J. Stine, and A. V. Demchenko.  A Streamlined regenerative glycosylation reaction: direct, acid-free activation of thioglycosides.  Chem. Eur. J., 2021, 27, 354-361 (Hot Paper) PMID: 32804435 (2R01-12, U01-26) https://doi.org/10.1002/chem.202003479

(197)📖 M. P. Mannino and A. V. Demchenko.  Hydrogen-bond-mediated Aglycone Delivery (HAD) and related methods in carbohydrate chemistry.  In “Carbohydrate Chemistry: Chemical and Biological Approaches,” Volume 44 (Specialist Periodical Reports), A. P. Rauter, T. K. Lindhorst, and Y. Queneau Eds., RSC, 2021, 93-116; https://doi.org/10.1039/9781788013864-00093 (3NSF-19)

(196) M. Shadrick, Y. Singh, and A. V. Demchenko.  Stereocontrolled α-galactosylation under cooperative catalysis.  J. Org. Chem., 2020, 85, 15936-15944 PMID: 33064474 (3NSF-18, 2R01-11) https://dx.doi.org/10.1021/acs.joc.0c01279

(195) G. Shrestha, M. Panza, Y. Singh, N. P. Rath, and A. V. Demchenko.  Indolylthio glycosides as effective building blocks for chemical glycosylation.  J. Org. Chem., 2020, 85, 15885-15894 PMID: 32627548 (3NSF-17, 2R01-10) https://doi.org/10.1021/acs.joc.0c00943

(194) S. Visansirikul, S. A. Kolodziej, and A. V. Demchenko.  Synthesis of oligosaccharide fragments of capsular polysaccharide Staphylococcus aureus type 8. J. Carbohydr. Chem., 2020, 39, 301-333 https://doi.org/10.1080/07328303.2020.1821042

(193) M. Panza, D. Neupane, K. J. Stine, and A. V. Demchenko.  The development of a dedicated polymer support for the solid-phase oligosaccharide synthesis.  Chem. Commun., 2020, 56, 10568-10571 PMID: 32785304 (2R01-9, U01-25) https://doi.org/10.1039/D0CC03885G

(192) C. Alex, S. Visansirikul, and A. V. Demchenko.  A versatile approach to the synthesis of mannosamine glycosides.  Org. Biomol. Chem., 2020, 18, 6682-6695 PMID: 32813001 (3NSF-16) https://doi.org/10.1039/D0OB01640C

(191) D. Neupane, J. K. Bhattarai, A. V. Demchenko, and K. J. Stine.  A pH sensitive thiolated β-cyclodextrin-modified nanoporous gold for controlled release of doxorubicin.  J. Drug Deliv. Sci. Technol., 2020, 101985 PMID: 32922527 (2R01-8, U01-24) https://doi.org/10.1016/j.jddst.2020.101985

(190) S. A. Geringer, M. P. Mannino, M. D. Bandara, and A. V. Demchenko.  Picoloyl protecting group in synthesis: focus on a highly chemoselective catalytic removal.  Org. Biomol. Chem., 2020, 18, 4863-4871 PMID: 32608450 (3NSF-15, 2R01-7) https://doi.org/10.1039/D0OB00803F

(189) S. A. Geringer, Y. Singh, D. J. Hoard, and A. V. Demchenko.  A highly efficient glycosidation of glycosyl chlorides using cooperative silver(I) oxide – triflic acid catalysis.  Chem. Eur. J., 2020, 26, 8053-8063 PMID: 32145116 (2R01-6, 3NSF-14) https://doi.org/10.1002/chem.201905576

(188) J. Bhattarai, D. Neupane, B. Nepal, M. D. Alharthi, A. V. Demchenko, and K. J. Stine.  Adhesion layer-free attachment of gold on silicon wafer and its application in localized surface plasmon resonance-based biosensing.  Sens. Actuators A: Phys., 2020, 312, 112155 PMID: 32647405 (2R01-5) https://doi.org/10.1016/j.sna.2020.112155

(187)📖 J. K. Bhattarai, D. Neupane, M. H. U. Maruf, A. V. Demchenko, and K. J. Stine.  Recent advances in the application of glycan-modified self-assembled monolayers.  In “Advances in Chemistry Research,” Volume 60, J. C. Taylor Ed., Nova Science Publishers, 2020, 95-119 PMID: 33224429 (2R01-4) ISBN: 978-1-53617-449-6

(186) M. D. Bandara, K. J. Stine, and A. V. Demchenko.  Chemical synthesis of human milk oligosaccharides: lacto-N-neohexaose [Galβ14GlcNAcβ1]2 3,6-Galβ14Glc.  Org. Biomol. Chem., 2020, 18, 1747-1753 (Front Cover) PMID: 32048706 (2R01-3, U01-23) https://doi.org/10.1039/D0OB00172D

(185) M. P. Mannino and A. V. Demchenko.  Synthesis of β-glucosides with 3-O-picoloyl-protected glycosyl donors in the presence of excess triflic acid: defining the scope.  Chem. Eur. J., 2020, 26, 2938-2946 (Hot Paper) PMID: 31886911 (3NSF-13) https://doi.org/10.1002/chem.201905278

(184) M. P. Mannino and A. V. Demchenko.  Synthesis of β-glucosides with 3-O-picoloyl-protected glycosyl donors in the presence of excess triflic acid: a mechanistic study.  Chem. Eur. J., 2020, 26, 2927-2937 (Hot Paper) PMID: 31886924 (3NSF-12) https://doi.org/10.1002/chem.201905277

(183) S. Visansirikul, S. A. Kolodziej, and A. V. Demchenko.  Staphylococcus aureus capsular polysaccharides: a structural and synthetic perspective.  Org. Biomol. Chem., 2020, 18, 783-798; PMID: 31922180 https://doi.org/10.1039/C9OB02546D

(182) M. Panza, K. J. Stine, and A. V. Demchenko.  HPLC-assisted automated oligosaccharide synthesis: the implementation of the two-way split valve as a mode of complete automation.  Chem. Commun., 2020, 56, 1333-1336 (Inside Back Cover) PMID: 31930269 (2R01-2, U01-22) https://doi.org/10.1039/C9CC08876H

(181) Y. Singh and A. V. Demchenko.  Defining the scope of the acid-catalyzed glycosidation of glycosyl bromides.  Chem. Eur. J., 2020, 26, 1042-1051 (Hot Paper) PMID: 31614042 (2R01-1, 3NSF-11) https://doi.org/10.1002/chem. 201904185 Front Cover Picture: https://doi.org/10.1002/chem.201905186 Cover Profile: Chem. Eur. J., 2020, 26, 963; PMID: 31815309; https://doi.org/10.1002/chem.201905187

(180) C. Alex, S. Visansirikul, Y. Zhang, J. P. Yasomanee, J. Codee, and A. V. Demchenko.  Synthesis of 2-azido-2-deoxy- and 2-acetamido-2-deoxy-D-manno derivatives as versatile building blocks.  Carbohydr. Res., 2020, 488, 107900; PMID: 31901454 (3NSF-10, U01-21) https://doi.org/10.1016/j.carres.2019.107900

(179) M. D. Bandara, K. J. Stine, and A. V. Demchenko.  Chemical synthesis of human milk oligosaccharides: lacto-N-hexaose Galβ1->3GlcNAcβ1->3[Galβ1->4GlcNAcβ1->6]Galβ1->4Glc.  J. Org. Chem., 2019, 84, 16192-16198 PMID: 31749363 (1R01-29, U01-20) https://doi.org/10.1021/acs.joc.9b02701

(178) M. P. Mannino, A. P. Dunteman, and A. V. Demchenko.  Carbohydrate experiments in the organic laboratory: a robust synthesis and modification of thioglycosides.  J. Chem. Educ., 2019, 96, 2322-2325; (U01-19, 3NSF-9) https://doi.org/10.1021/acs.jchemed.9b00446

(177) Y. Singh, T. Wang, and A. V. Demchenko.  Direct glycosidation of 2-azido-2-deoxyglycosyl nitrates.  Eur. J. Org. Chem., 2019, 6413-6416; (U01-18, 3NSF-8) https://doi.org/10.1002/ejoc.201900748

(167) T. Wang, Y. Singh, K. J. Stine, and A. V. Demchenko.  Investigation of glycosyl nitrates as building blocks for chemical glycosylation.  Eur. J. Org. Chem., 2018, 6699-6705; PMID: 31341403 (U01-10, 3NSF-3) https://doi.org/10.1002/ejoc.201801272

(166) S. A. Geringer and A. V. Demchenko.  Iron(III) Chloride-Catalyzed Activation of Glycosyl Chlorides.  Org. Biomol. Chem., 2018, 16, 9133-9137 PMID: 30430182 (U01-9; 3NSF-2)  https://doi.org/10.1039/C8OB02413H

(165) C. L. O’Neil, K. J. Stine, and A. V. Demchenko.  Immobilization of glycans on solid surfaces for application in glycomics.  J. Carbohydr. Chem., 2018, 37, 225-249 PMID: 30505067 (1R01-26, U01-8) https://doi.org/10.1080/07328303.2018.1462372

(164) M. P. Mannino, J. P. Yasomanee, and A. V. Demchenko.  Investigation of the H-bond-mediated aglycone delivery reaction in application to the synthesis of β-glucosides.  Carbohydr. Res., 2018, 470, 1-7 PMID: 30286335 (U01-7, 3NSF-1) https://doi.org/10.1016/j.carres.2018.09.003

(163) M. Panza, S. G. Pistorio, K. J. Stine, A. V. Demchenko.  Automated chemical oligosaccharide synthesis: novel approach to traditional challenges.  Chem. Rev., 2018, 118, 8105-8150 PMID: 29953217 (1R01-25, U01-6) https://doi.org/10.1021/acs.chemrev.8b00051

(162)📖 J. K. Bhattarai, D. Neupane, B. Nepal, V. Mikhaylov, A. V. Demchenko, K. J. Stine.  Structure and Applications of Gold in Nanoporous Form. In “Noble and Precious Metals – Properties, Nanoscale Effects and Applications.” M. Seehra Ed. IntechOpen: Rijeka, 2018, 341-365 ISBN 978-953-51-5771-7 (1R01-24) https://doi.org/10.5772/intechopen.71439

(161) T. Wang, S. S. Nigudkar, J. P. Yasomanee, N. P. Rath, K. J. Stine, A. V. Demchenko.  Glycosyl nitrates in synthesis: streamlined access to glucopyranose building blocks differentiated at C-2.  Org. Biomol. Chem., 2018, 6, 3596-3604; PMID: 29693690 (1R01-23, U01-5) https://doi.org/10.1039/C8OB00477C

(160) J. K. Bhattarai, D. Neupane, B. Nepal, V. Mikhaylov, A. V. Demchenko, K. J. Stine.  Preparation, Modification, Characterization, and Biosensing Application of Nanoporous Gold Using Electrochemical Techniques.  Nanomaterials, 2018, 8, 171 PMID: 29547580 (1R01-22) https://doi.org/10.3390/nano8030171

(159) Y. Singh, T. Wang, S. A. Geringer, K. J. Stine, A. V. Demchenko.  Regenerative glycosylation.  J. Org. Chem., 2018, 83, 374-381 PMID: 29227649 (1R01-21, U01-4) https://doi.org/10.1021/acs.joc.7b02768

(158) X. G. Jia and A. V. Demchenko.  Intramolecular glycosylation.  Beilstein J. Org. Chem. 2017, 13, 2028-2048; PMID: 29062425 (1R01-20, U01-3) https://doi.org/10.3762/bjoc.13.201

(157)📖 J. K. Bhattarai, V. Mikhaylov, D. Neupane, B. Nepal, A. V. Demchenko, K. J. Stine.  Carbohydrate-protein interactions study using electrochemical impedance spectroscopy.  In “Electrochemical Impedance Spectroscopy: Methods, Analysis and Research,” J. Brock Ed., Nova Science Publisher, Inc., 2017, 1-26 (front cover) (1R01-19) ISBN: 978-1-53611-857-5   

(156)📖 M. P. Mannino, J. P. Yasomanee, A. V. Demchenko, V. Patteti.  Picoloyl group in oligosaccharide synthesis: installation, H-bond-mediated aglycone delivery (HAD), and selective removal.  In “Carbohydrate Chemistry: Proven Synthetic Methods,” Volume 4, P. Murphy and C. Vogel Eds., CRC Press, 2017, 3-10 (2NSF-20, 1R01-18) https://doi.org/10.1201/9781315120300

(155)📖 J. K. Bhattarai, D. Neupane, V. Mikhaylov, A. V. Demchenko, K. J. Stine.  Localized surface plasmon resonance-active surfaces applied to study interactions of biomolecules.  In “Surface Plasmon Resonance (SPR),” D. Howell Ed., Nova Science Publisher, Inc., 2017, 87-122 (1R01-17); ISBN: 978-1-53611-857-5

(154) S. J. Hasty, N. P. Rath, A. V. Demchenko.  Extending the S-benzimidazolyl platform: N-alkylated SBiz glycosyl donors with the universal activation profile.  Pure Appl. Chem., 2017, 89, 1321-1331 PMID: 29861508 (1R01-16, U01-2) https://doi.org/10.1515/pac-2017-0112

(153)📖  J. K. Bhattarai, D. Neupane, V. Mikhaylov, A. V. Demchenko, K. J. Stine.  Self-assembled monolayers of carbohydrate derivatives on gold surfaces. In “Carbohydrate,” M. Caliskan, I. H. Kavakli, G. C. Oz, Eds., InTech: Rijeka, 2017, 63-97 (1R01-15) https://doi.org/10.5772/66194  

(152) S. J. Hasty, M. D. Bandara, N. P. Rath, A. V. Demchenko.  S-Benzimidazolyl (SBiz) imidates as a platform for oligosaccharide synthesis via active-latent, armed-disarmed, selective and orthogonal activations.  J. Org. Chem., 2017, 82, 1904-1911 PMID: 28135419 (3R15-18, 1R01-14) https://doi.org/10.1021/acs.joc.6b02478

(151) M. D. Bandara, J. P. Yasomanee, N. P. Rath, C. M. Pedersen, M. Bols, A. V. Demchenko.  Conformationally superarmed S-ethyl glycosyl donors as effective building blocks for chemoselective oligosaccharide synthesis in one pot.  Org. Biomol. Chem., 2017, 15, 559-563 PMID: 27942674 (1R01-13) https://doi.org/10.1039/C6OB02498J

(150)📖 M. D. Bandara, J. P. Yasomanee, A. V. Demchenko.  Application of armed, disarmed, superarmed and superdisarmed building blocks in stereocontrolled glycosylation and expeditious oligosaccharide synthesis. In “Selective Glycosylations: Synthetic Methods and Catalysts,” C. S. Bennett Ed., Wiley, 2017, 29-58 (1R01 12) https://doi.org/10.1002/9783527696239.ch2  

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10. S. Nigudkar, T. Wang, S. G. Pistorio, J. P. Yasomanee, K. J. Stine, A. V. Demchenko.  OFox imidates as versatile glycosyl donors for chemical glycosylation. Org. Biomol. Chem., 2017, 15, 348-359 (front cover; hot paper; featured by the RSC);  PMID: 27808325 (1R01-11, U01-1) https://doi.org/10.1039/C6OB02230H

(148) X. G. Jia, P. Pornsuriyasak, A. V. Demchenko.  Templated oligosaccharide synthesis: driving forces and mechanistic aspects. J. Org. Chem., 2016, 81, 12232-12246 PMID: 27978734 (1R01-10) https://doi.org/10.1021/acs.joc.6b02151 

147) A. Sharma, J. K. Bhattarai, S. S. Nigudkar, S. G. Pistorio, A. V. Demchenko, K. J. Stine.  Electrochemical impedance spectroscopy study of carbohydrate-terminated alkanethiol monolayers on nanoporous gold: implications for pore wetting. J. Electroanal. Chem., 2016, 782, 174-181 PMID: 28413373 (1R01-9) https://doi.org/10.1016/j.jelechem.2016.10.013

146) J. K. Bhattarai, Y. H. Tan, B. Pandey, K. Fujikawa, A. V. Demchenko, K. J. Stine.  Electrochemical impedance spectroscopy study of Concanavalin A binding to self-assembled monolayers of mannosides on gold wire electrodes. J. Electroanal. Chem., 2016, 780, 311-320 PMID: 28413372 (1R01-8) https://doi.org/10.1016/j.jelechem.2016.09.045

(145) S. G. Pistorio, S. S. Nigudkar, K. J. Stine, A. V. Demchenko.  HPLC-assisted automated oligosaccharide synthesis: the implementation of the autosampler as a mode of the reagent delivery.  J. Org. Chem., 2016, 81, 8796−8805 PMID: 27575052 (1R01-7) https://doi.org/10.1021/acs.joc.6b01439

(144) J. P. Yasomanee, S. Visansirikul, P. Pornsuriyasak, M. Thompson, S. A. Kolodziej, A. V. Demchenko.  Synthesis of the repeating unit of capsular polysaccharide Staphylococcus aureus type 5 to study chemical activation and conjugation of native CP5.  J. Org. Chem., 2016, 81, 5981−5987; PMID: 27305525 (Pfizer-2) https://doi.org/10.1021/acs.joc.6b00910

(143) P. Pornsuriyasak, X. G. Jia, S. Kaeothip, A. V. Demchenko.  Templated oligosaccharide synthesis: the linker effect on the stereoselectivity of glycosylation.  Org. Lett., 2016, 18, 2316-2319; PMID: 27115718 (1R01-6) https://doi.org/10.1021/acs.orglett.6b01102

(142) J. P. Yasomanee, A. R. Parameswar, P. Pornsuriyasak, N. P. Rath, A. V. Demchenko. 2,3-Di-O-picolinyl building blocks as glycosyl donors with switchable stereoselectivity. Org. Biomol. Chem., 2016, 14, 3159–3169 PMID: 26911322 (2NSF-19, Mizu-4) https://doi.org/10.1039/c6ob00107f

(141) A. J. Alla, F. B. d’Andrea, J. K. Bhattarai, J. A. Cooper; Y. H. Tan, A. V. Demchenko, K. J. Stine.  Selective capture of glycoproteins using lectin-modified nanoporous gold monolith. J. Chromatogr. A., 2015, 1423, 19-30 PMID: 26554297 (1R01-5, R01S-16) https://doi.org/10.1016/j.chroma.2015.10.060

(140) A. K. Kayastha, X. G. Jia, J. P. Yasomanee, A. V. Demchenko.  6-O-Picolinyl and 6-O-picoloyl building blocks as glycosyl donors with switchable stereoselectivity.  Org. Lett., 2015, 17, 4448-4451 PMID: 26349759 (2NSF-18, Mizu-3) https://doi.org/10.1021/acs.orglett.5b02110

(139)📖 S. G. Pistorio, K. J. Stine, A. V. Demchenko.  Automated chemical synthesis of oligosaccharides and glycoconjugates. In “Carbohydrate Chemistry: State-of-the-art and challenges for drug development,” L. Cipolla Ed., Imperial College Press, London, 2015, 247-276 (1R01-4, R01S-15) https://doi.org/10.1142/9781783267200_0010

(130) A. F. B. White and A. V. Demchenko.  Modulating LPS signal transduction at the LPS receptor complex with synthetic Lipid-A analogues.  Adv. Carbohydr. Chem. Biochem., 2014, 71, 339-389 PubMed ID: 25480508 (1R01-1) https://doi.org/10.1016/B978-0-12-800128-8.00005-4

(129) J. P. Yasomanee and A. V. Demchenko.  Hydrogen bond mediated aglycone delivery: synthesis of linear and branched α-glucans.  Angew. Chem. Int. Ed., 2014, 53, 10453–10456 PubMed ID: 25115776 (2NSF-12, Mizu-1) https://doi.org/10.1002/anie.201405084

(128) J. Gyore, A. R. Parameswar, C. Hebbard, Y. Oh, E. Bi, A. V. Demchenko, N. P. Price, P. Orlean.  2-Acylamido analogues of N-acetylglucosamine prime formation of chitin oligosaccharides by yeast chitin synthase 2.  J. Biol. Chem., 2014, 289, 12835-12841PubMed ID: 24619411 (3R15-16) https://doi.org/10.1074/jbc.M114.550749

(127)📖 P. Pornsuriyasak, J. P. Yasomanee, E. I. Balmond, C. De Meo, A. V. Demchenko.  Synthesis of 4,6-O-benzylidene acetals of methyl α-D-glucopyranoside, ethyl 1-thio-β-D-gluco- and galactopyranoside.  In “Carbohydrate Chemistry: Proven Synthetic Methods,” Volume 2, G. van der Marel and J. Codee Eds., CRC Press, 2014, 189-196 (2NSF-11) https://doi.org/10.1201/b16602

(126)📖 S. S. Nigudkar, S. J. Hasty, M. Varese, P. Pornsuriyasak, A. V. Demchenko.  Synthesis of 1,3,4,6-tetra-O-acetyl-a-D-glucopyranose revisited.  In “Carbohydrate Chemistry: Proven Synthetic Methods,” Volume 2, G. van der Marel and J. Codee Eds., CRC Press, 2014, 183-187 (2NSF-10) https://doi.org/10.1201/b16602

(125) S. J. Hasty, S. C. Ranade, A. V. Demchenko.  A study of silver(I) perchlorate as an effective promoter for chemical glycosylation with thioimidates and thioglycosides. Reports Org. Chem., 2014, 4, 1-10 (2NSF-9) https://doi.org/10.2147/ROC.S32147

(124) S. G. Pistorio, J. P. Yasomanee, A. V. Demchenko.  Hydrogen bond-mediated aglycone delivery: focus on β-mannosylation.  Org. Lett., 2014, 16, 716−719 PubMed ID: 24471826 (2NSF-8) https://doi.org/10.1021/ol403396j

(123) B. Pandey, J. K. Bhattarai, P. Pornsuriyasak, K. Fujikawa, R. Catania, A. V. Demchenko, K. J. Stine.  Square-wave voltammetry assays for glycoproteins on nanoporous gold.  J. Electroanal. Chem., 2014, 717-718, 47-60 (R01S-12) https://doi.org/10.1016/j.jelechem.2014.01.009

(122) S. S. Nigudkar, K. J. Stine, A. V. Demchenko.  Regenerative glycosylation under nucleophilic catalysis.  J. Am. Chem. Soc., 2014, 136, 921-923 PubMed ID: 24393099 (3R15-15, R01S-11) https://doi.org/10.1021/ja411746a

(121)   J. A. Hawkins-Salsbury, A. R. Parameswar, X. Jiang, P. H. Schlesinger, E. Bongarzone, D. S. Ory, A. V. Demchenko, M. S. Sands.  Psycosine, the cytotoxic sphingolipid that accumulates in globoid cell leukodystrophy, alters membrane architecture.  J. Lipid Res., 2013, 54, 3303-3311; PubMed ID: 24006512 (3R15-14) https://doi.org/10.1194/jlr.M039610

(120)   M. Heuckendorff, H. D. Premathilake, P. Pornsuriyasak, A. O. Madsen, C. M. Pedersen, M. Bols, A. V. Demchenko.  Superarming of glycosyl donors by combined neighboring and conformational effects.  Org. Lett., 2013, 15, 4904-4907; (3R15-13) https://doi.org/10.1021/ol402371b

(119)   S. C. Ranade, S. J. Hasty, A. V. Demchenko.  A comparative study of glycosyl thioimidates as building blocks for chemical glycosylation.  J. Carbohydr. Chem., 2013, 32, 360-379 (3R15-12, 2NSF-7) https://doi.org/10.1080/07328303.2013.826670

(118)   N. Vijaya Ganesh, K. Fujikawa, Y. H. Tan, S. S. Nigudkar, K. J. Stine, A. V. Demchenko.  Surface-Tethered Iterative Carbohydrate Synthesis: a spacer study.  J. Org. Chem., 2013, 78, 6849−6857 (featured article) PubMed ID: 23822088 (R01-10) https://doi.org/10.1021/jo400095u

(117) E. Alverson-Banks Avegno, S. J. Hasty, A. R. Parameswar, G. Howarth, A. V. Demchenko, L. D. Byers.  Reactive thioglucoside substrates for β-glucosidase. Arch. Biochem. Biophys., 2013, 537, 1-4 PubMed ID: 23811198 (3R15-11) https://doi.org/10.1016/j.abb.2013.06.010

(116)   Y. H. Tan, K. Fujikawa, P. Pornsuriyasak, A. Alla, N. Vijaya Ganesh, A. V. Demchenko, K. J. Stine.  Lectin-carbohydrate interactions on nanoporous gold monoliths.  New J. Chem., 2013, 37, 2150-2165 (R01-9) https://doi.org/10.1039/c3nj00253e

(115)   S. S. Nigudkar, A. R. Parameswar, P. Pornsuriyasak, K. J. Stine, A. V. Demchenko.  O-Benzoxazolyl imidates as versatile glycosyl donors for chemical glycosylation.  Org. Biomol. Chem., 2013, 11, 4068-4076 (3R15-10, R01-8) https://doi.org/10.1039/c3ob40667a

(114)   B. Pandey, Y. H. Tan, A. R. Parameswar, P. Pornsuriyasak, A. V. Demchenko, K. J. Stine.  Electrochemical characterization of globotriose containing self-assembled monolayers on nanoporous gold and their binding of soybean agglutinin.  Carbohydr. Res., 2013, 373, 9-17; PubMed ID: 23545324 (R01-7) https://doi.org/10.1016/j.carres.2012.09.021

(113) J. P. Yasomanee and A. V. Demchenko.  From stereocontrolled chemical glycosylation to expeditious oligosaccharide synthesis.  Trends Glycosci. Glycotechnol., 2013, 25, 13-42 (3R15-9, 2NSF-6) https://doi.org/10.4052/tigg.25.13

(112) S. C. Ranade and A. V. Demchenko.  Mechanism of chemical glycosylation: focus on the mode of activation and departure of anomeric leaving groups.  J. Carbohydr. Chem., 2013, 32, 1-43 (2NSF-5, 3R15-8) https://doi.org/10.1080/07328303.2012.749264

(111) J. Yao, J. Xia, K. I. Maslov, M. Nasiriavanaki, V. Tsytsarev, A. V. Demchenko, L. V. Wang.  Noninvasive photoacoustic computed tomography of mouse brain metabolism in vivo.  NeuroImage, 2013, 64, 257-266; PubMed ID: 22940116 https://doi.org/10.1016/j.neuroimage.2012.08.054

(110)    J. P. Yasomanee and A. V. Demchenko.  Effect of remote picolinyl and picoloyl substituents on the stereoselectivity of chemical glycosylation.  J. Am. Chem. Soc., 2012, 134, 20097−20102; DOI: 10.1021/ja307355n (2NSF-4)

(109)    B. Pandey, A. V. Demchenko, K. J. Stine.  Nanoporous gold as a solid support for protein immobilization and development of an electrochemical immunoassay for prostate specific antigen and carcinoembryonic antigen.  Microchim. Acta, 2012, 179, 71-81; DOI: 10.1007/s00604-012-0870-x (R01-6)

(108)    B. Pandey, Y. H. Tan, K. Fujikawa, A. V. Demchenko, K. J. Stine.  Comparative study of the binding of concanavalin A to self-assembled monolayers containing a thiolated α-mannoside on flat gold and on nanoporous gold.  J. Carbohydr. Chem., 2012, 31, 466-503; DOI: 10.1080/ 07328303.2012.683909 (R01-5) 

(107)    N. Vijaya Ganesh, K. Fujikawa, Y. H. Tan, K. J. Stine, A. V. Demchenko.  HPLC-assisted automated oligosaccharide synthesis.  Org. Lett., 2012, 14, 3036-3039; DOI: 10.1021/ol301105y; PubMed ID: 22646669 (R01-4, 3R15-7)

(106)    S. J. Hasty and A. V. Demchenko.  Glycosyl thioimidates as versatile building blocks for organic synthesis.  Chem. Heterocycl. Compd., 2012, 48, 220-240; Khimiya Geterotsiklicheskikh Soedinenii, 229-250; DOI: 10.1007/s10593-012-0984-4 (2NSF-3, 3R15-6) 

(105)    H. D. Premathilake and A. V. Demchenko.  2-Allylphenyl glycosides as complementary building blocks for oligosaccharide and glycoconjugate synthesis.  Beilstein J. Org. Chem., 2012, 8, 597-605; DOI: 10.3762/bjoc.8.66 (3R15-5)

(104)    Y. H. Tan, J. A. Davis, K. Fujikawa, N. Vijaya Ganesh, A. V. Demchenko, K. J. Stine.  Surface area and pore size characteristics of nanoporous gold subjected to thermal, mechanical, or surface modification studied using gas adsorption isotherms, cyclic voltammetry, thermogravimetric analysis, and scanning electron microscopy.  J. Mater. Chem., 2012, 22, 6733-6745; DOI: 10.1039/c2jm16633j (R01-3)

(103)    H. D. Premathilake, C. P. Gobble, P. Pornsuriyasak, T. Hardimon, A. V. Demchenko, C. De Meo.  How O-substitution of sialyl donors affects their stereoselectivity.  Org. Lett., 2012, 14, 1126-1129; DOI: 10.1021/ol3000475; PubMed ID: 22300507 (2NSF-2)

(102)^📖  A. R. Parameswar, A. Imamura, A. V. Demchenko.  Synthesis of thioglycosides and thioimidates from peracetates.  In “Carbohydrate Chemistry: Proven Synthetic Methods,” Volume 1, P. Kovac Ed., CRC Press, 2012, pp 187-196 https://doi.org/10.1201/b11261  (NSF-21)

(101)^📖  A. R. Parameswar, D. Mueller, L. Liu, C. De Meo, A. V. Demchenko.  Synthesis of thioglycosides and thioimidates from glycosyl halides.  In “Carbohydrate Chemistry: Proven Synthetic Methods,” Volume 1, P. Kovac Ed., CRC Press, 2012, pp 181-186 https://doi.org/10.1201/b11261  (NSF-20)

(100)    S. Kaeothip, J. P. Yasomanee, A. V. Demchenko.  Glycosidation of thioglycosides in the presence of bromine: mechanism, reactivity, and stereoselectivity.  J. Org. Chem., 2012, 77, 291-299; DOI: 10.1021/jo2019174 (NSF-19, 2NSF-1)

(99)      V. Tsytsarev, K. I. Maslov, J. Yao, A. R. Parameswar, A. V. Demchenko, L. V. Wang.  In vivo imaging of epileptic activity using 2-NBDG, a fluorescent deoxyglucose analog.  J. Neurosci. Methods, 2012, 203, 136-140; DOI: 10.1016/j.jneumeth.2011.09.005; PubMed ID: 21939688 (2R15-14, 3R15-4)

(98)      M. V. Roux, M. Temprado, P. Jimenez, R. Notario, A. R. Parameswar, A. V. Demchenko, J. S. Chickos, C. A. Deakyne, J. F. Liebman.  Knowledge of a molecule: an experimental and theoretical study of the structure and enthalpy of formation of tetrahydro-2H-1,3-oxazine-2-thione. J. Chem. Eng. Data, 2011, 56, 4725-4732

(97)      K. Fujikawa, N. Vijaya Ganesh, Y. H. Tan, K. J. Stine, A. V. Demchenko.  Reverse orthogonal approach to oligosaccharide synthesis.  Chem. Commun., 2011, 47, 10602-10604 (R01-2, 2R15-13, 3R15-3)

(96)      S. Kaeothip, A. V. Demchenko.  On orthogonal and selective activation of glycosyl thioimidates and thioglycosides: application to oligosaccharide assembly.  J. Org. Chem., 2011, 76, 7388–7398  (2R15-12, R03-3, 3R15-2)

(95)      S. Kaeothip, G. Paranjape, S. E. Terrill, A. F. G. Bongat, M. L. D. Udan, T. Kamkhachorn, H. L. Johnson, M. R. Nichols, A. V. Demchenko.  Development of LPS antagonistic therapeutics: synthesis and evaluation of glucopyranoside-spacer-amino acid motifs.  RSC Adv., 2011, 1, 83-92 (AHA.08-10)

(94)      Y. H. Tan, J. R. Schallom, N. Vijaya Ganesh, K. Fujikawa, A. V. Demchenko, K. J. Stine.  Characterization of protein immobilization on nanoporous gold using atomic force microscopy and scanning electron microscopy. Nanoscale, 2011, 3, 3395-3407 (R01-1)

(93)      S. Kaeothip and A. V. Demchenko.  Expeditious oligosaccharide synthesis via selective and orthogonal activation.  Carbohydr. Res., 2011, 346, 1371-1388 (Special issue) (2R15-11, 3R15-1)

(92)      L. K. Mydock, M. N. Kamat, A. V. Demchenko.  Direct synthesis of diastereomerically pure glycosyl sulfonium salts. Org. Lett., 2011, 13, 2928-2931 (NSF-18, 2R15-10)

(91)      S. J. Hasty, M. Kleine, A. V. Demchenko.  S-Benzimidazolyl glycosides as a platform for oligosaccharide synthesis by an active-latent strategy.  Angew. Chem. Int. Ed., 2011, 50, 4197-4201; DOI: 10.1002/anie.201007212 (2R15-9, R03-2, AHA.08-9)

(90)📖   H. D. Premathilake, A. V. Demchenko.  Superarmed and superdisarmed building blocks in expeditious oligosaccharide synthesis.  In “Topics in Current Chemistry, Vol. 301. Reactivity Tuning in Oligosaccharide Assembly.” B. Fraser-Reid, J. C. Lopez Eds., Springer-Verlag, Berlin-Heidelberg, 2011, pp. 189-221 (2R15-8)

(89)      L. K. Mydock, C. D. Spilling, A. V. Demchenko.  Concise synthesis of 1,3-di-O-substituted tetrahydropyran derivatives as conformationally restricted pyranose mimetics.  Comptes Rendus Chimie, 2011, 14, 301-306 (Special issue) (NSF-17)

(88)^📖    A. V. Demchenko, C. De Meo.  Product class 16: glycosyl oxygen compounds (di- and oligosaccharides). In Science of Synthesis, Houben-Weyl Methods of Molecular Transformations., SOS Knowledge Updates, Volume 2010/3: Ishihara, K; Procter, D. J.; Schaumann E. Eds., Georg Thieme Verlag KG, Stuttgart – New York, 2011, pp. 229-415

(87)      S. C. Ranade, S. Kaeothip, A. V. Demchenko.  Glycosyl alkoxythioimidates as complementary building blocks for chemical glycosylation. Org. Lett., 2010, 12, 5628-5631 (2R15-7, NSF-16, AHA.08-8)

(86)      C. A. Deakyne, A. K. Ludden, M. V. Roux, R. Notario, A. V. Demchenko, J. S. Chickos, J. F. Liebman.  Energetics of the lighter chalcogen analogues of carboxylic acid esters.  J. Phys. Chem. B, 2010, 114, 16253-16262

(85)      A. V. Demchenko.  Carbohydrates: Synthesis, Mechanisms, and Stereoelectronic Effects. By Momcilo Miljkovic (Pennsylvania State University, Hershey, PA, USA). Springer Science + Business Media: New York. 2010. xvi + 544 pp. $199. ISBN 978-0-387-92264-5.  J. Am. Chem. Soc., 2010, 132, 16297

(84)      S. Kaeothip, S. J. Akins, A. V. Demchenko.  On the stereoselectivity of glycosidation of thiocyanates, thioimidates, and thioglycosides.  Carbohydr. Res., 2010, 345, 2146-2150 (NSF-15, AHA.08-7)  

(83)      C. Vetter, P. Pornsuriyasak, J. Schmidt, N. P. Rath, T. Rüffer, A. V. Demchenko, D. Steinborn.  Synthesis, characterization and reactivity of carbohydrate platinum(IV) complexes with thioglycoside ligands. Dalton Trans., 2010, 39, 6327-6338  (NSF-14, 2R15-6)

(82)      T. Kamkhachorn, A. R. Parameswar, A. V. Demchenko.  Comparison of the armed/disarmed building blocks of the D-gluco and D-glucosamino series in the context of chemoselective oligosaccharide synthesis.  Org. Lett., 2010, 12, 3078-3081  (AHA.08-6, 2R15-5)

(81)      A. R. Parameswar, J. A. Hawkins, L. K. Mydock, M. S. Sands, A. V. Demchenko.  Concise synthesis of the unnatural sphingosine and psychosine enantiomer.  Eur. J. Org. Chem., 2010, 3269-3274 (NSF-13, AHA.08-5)

(80)      M. V. Roux, M. Temprado, P. Jiménez, C. Foces-Foces, R. Notario, A. R. Parameswar, A. V. Demchenko, J. S. Chickos, C. A. Deakyne, J. F. Liebman.  Experimental and theoretical study of the structures and enthalpies of formation of 3H-1,3-benzoxazole-2-thione, 3H-1,3-benzothiazole-2-thione, and their tautomers.  J. Phys. Chem. A, 2010, 114, 6336-6341 (AHA.08-4, NSF-12)

(79)      H. D. Premathilake, L. K. Mydock, A. V. Demchenko.  Superarming common glycosyl donors by simple 2-O-benzoyl-3,4,6-tri-O-benzyl protection.  J. Org. Chem., 2010, 75, 1095-1100 (2R15-4, NSF-11)

(78)      L. K. Mydock, A. V. Demchenko.  Mechanism of chemical O-glycosylation: from early studies to recent discoveries.  Org. Biomol. Chem., 2010, 8, 497-510 (NSF-10)

(77)      A. R. Parameswar, I. H. Park, R. Saksena, P. Kovac, M. H. Nahm, A. V. Demchenko.  Synthesis, congugation, and immunological evaluation of the serogroup 6 pneumococcal oligosaccharides.  ChemBioChem, 2009, 10, 2893-2899 (R03-1, NSF-9)

(76)      P. Pornsuriyasak, C. Vetter, S. Kaeothip, M. Kovermann, J. Balbach, D. Steinborn, A. V. Demchenko.  Coordination chemistry approach to the long-standing challenge of anomeric stereoselectivity.  Chem. Commun., 2009, 6379-6381 (NSF-8, AHA.08-3)

(75)      M. V. Roux, M. Temprado, P. Jiménez, C. Foces-Foces, R. Notario, A. R. Parameswar, A. V. Demchenko, J. S. Chickos, C. A. Deakyne, A. K. Ludden, J. F. Liebman.  Experimental and theoretical study of the structures and enthalpies of formation of the synthetic reagents 1,3-thiazolidine-2-thione and 1,3-oxazolidine-2-thione.  J. Phys. Chem. A, 2009, 113, 10772-10778 (AHA.08-2, NSF-7)

(74)      S. Park, A. R. Parameswar, A. V. Demchenko, M. H. Nahm.  Identification of a simple chemical structure associated with protective human antibodies against multiple pneumococcal serogroups.  Infect. Immun., 2009, 77, 3374-3379 (NSF-6)

(73)^    A. R. Parameswar, A. V. Demchenko.  One-pot oligosaccharide synthesis.  In “Progress in the synthesis of complex carbohydrate chains of plant and microbial polysaccharides”, N. E. Nifantiev Ed., Research Signpost and Transworld Research Network Publishers, Kerala, 2009, pp. 463-488

(72)      J. T. Smoot, A. V. Demchenko.  Oligosaccharide synthesis: from conventional methods to modern expeditious strategies.  Adv. Carbohydr. Chem. Biochem.  2009, 62, 161-250

(71)      P. Pornsuriyasak, S. C. Ranade, A. Li, M. C. Parlato, C. R. Sims, O. V. Shulga, K. J. Stine, A. V. Demchenko.  STICS: surface-tethered iterative carbohydrate synthesis.  Chem. Commun. 2009, 1834-1836 (R21-4, NSF-5)

(70)      S. Kaeothip, P. Pornsuriyasak, N. P. Rath, A. V. Demchenko.  Unexpected orthogonality of S-benzoxazolyl and S-thiazolinyl derivatives: application to expeditious oligosaccharide assembly.  Org. Lett., 2009, 11, 799-802 (2R15-3, AHA.08-1)

(69)^📖    A. V. Demchenko.  In the laboratory during 1988-1995. In Laboratory of carbohydrate and nucleotide chemistry ICNP – laboratory of carbohydrate chemistry IOC. Fifty years. A collection of memoirs. Y. A. Knirel Ed., ZIOC RAS, Moscow, 2009, pp. 233-238

(68)      J. T. Smoot, A. V. Demchenko.  How the arming participating moieties can broaden the scope of chemoselective oligosaccharide synthesis by allowing the inverse armed-disarmed approach.  J. Org. Chem. 2008, 73, 8838-8850 (2R15-2, PRF-5)

(67)      P. Pornsuriyasak, N. P. Rath, A. V. Demchenko.  4-(Pyridin-2-yl)thiazol-2-yl thioglycosides as bidentate ligands for oligosaccharide synthesis via temporary deactivation.  Chem. Commun. 2008, 5633-5635 (2R15-1)

(66)^📖    A. F. G. Bongat, A. V. Demchenko.  Catechol, first update.  In Encyclopedia of Reagents for Organic Synthesis, L. Paquette, P. Fuchs, D. Crich, and P. Wipf Eds., John Wiley & Sons, Ltd, 2008 (DOI: 10.1002/047084289X.rc031.pub2)

(65)^📖    A. R. Parameswar, A. V. Demchenko.  2-Chloro-1,1-diethoxyethane, first update.  In Encyclopedia of Reagents for Organic Synthesis, L. Paquette, P. Fuchs, D. Crich, and P. Wipf Eds., John Wiley & Sons, Ltd, 2008 (DOI: 10.1002/047084289X.rc086.pub2)

(64)      A. R. Parameswar, S. J. Hasty, A. V. Demchenko. Synthesis of spacer-containing analogs of serogroup 6 pneumococcal oligosaccharides.  Carbohydr. Res. 2008, 343, 1707-1717 (Special issue) (NSF-4)

(63)      L. K. Mydock, A. V. Demchenko.  Application of the superarmed glycosyl donor to chemoselective oligosaccharide synthesis.  Org. Lett. 2008, 10, 2107-2110 (R15-7)

(62)      L. K. Mydock, A. V. Demchenko.  Superarming the S-benzoxazolyl glycosyl donors by simple 2-O-benzoyl-3,4,6-tri-O-benzyl protection.  Org. Lett. 2008, 10, 2103-2106 (R15-6)

(61)      O. V. Shulga, D. Zhou, A. V. Demchenko, K. J. Stine.  Detection of free prostate specific antigen (fPSA) on a new nanoporous gold platform.  The Analyst  2008, 133, 319-322 (R21-3)

(60)^📖    A. V. Demchenko.  General aspects of the glycosidic bond formation. In Handbook of Chemical Glycosylation, A. V. Demchenko Ed., Wiley-VCH, Weinheim, 2008, pp. 1-27

(59)      M. C. Parlato, M. N. Kamat, H. S. Wang, K. J. Stine, A. V. Demchenko.  Application of glycosyl thioimidates in solid-phase oligosaccharide synthesis.  J. Org. Chem. 2008, 73, 1716-1725 (R21-2)

(58)      M. Temprado, M. V. Roux, A. R. Parameswar, A. V. Demchenko, J. S. Chickos, J. F. Liebman.  Thermophysical properties in medium temperature range of several thio and dithiocarbamates.  J. Therm. Anal. Cal. 2008, 91, 471-475. (R15-5)

(57)      S. Kaeothip, P. Pornsuriyasak, A. V. Demchenko.  Silver(I) tetrafluoroborate as a potent promoter for chemical glycosylation.  Tetrahedron Lett.  2008, 49, 1542-1545 (R15-4, AHA-3)

(56)      M. N. Kamat, C. De Meo, A. V. Demchenko.  S-Benzoxazolyl as a stable protecting moiety and a potent anomeric leaving group in oligosaccharide synthesis.  J. Org. Chem. 2007, 72, 6947-6955. (R15-3)

(55)      M. N. Kamat, N. P. Rath, A. V. Demchenko.  Versatile synthesis and mechanism of activation of S-benzoxazolyl glycosides.  J. Org. Chem. 2007, 72, 6938-6946. (R15-2)

(54)      A. R. Parameswar, P. Pornsuriyasak, N. A. Lubanowski, A. V. Demchenko.  Efficient stereoselective synthesis of oligosaccharides of Streptococcus pneumoniae serotypes 6A and 6B containing multiple 1,2-cis glycosidic linkages. Tetrahedron, 2007, 63, 10083-10091. (PRF-4, NSF-3) 

(53)      O. V. Shulga, K. Jefferson, A. R. Khan, V. T. D’Souza, J. Liu, A. V. Demchenko, K. J. Stine.  Preparation and characterization of porous gold and its application as a platform for immobilization of acetylcholine esterase. Chem. Mater. 2007, 19, 3902-3911. (R21-1)

(52)^📖    C. De Meo, G. J. Boons, A. V. Demchenko.  Synthesis of glycosides of sialic acid: chemical aspects (scope and limitations).  In Comprehensive Glycoscience – From Chemistry to Systems Biology.  J. P. Kamerling Ed., Elsevier, 2007, published July 2007

(51)^📖    A. V. Demchenko, C. De Meo.  Product class 16: glycosyl oxygen compounds (di- and oligosaccharides). In Science of Synthesis, Houben-Weyl Methods of Molecular Transformations, D. Bellus, E. N. Jacobsen, S. V. Ley, R. Noyori, M. Regitz, P. J. Reider, E. Schaumann, I. Shinkai, E. J. Thomas and B. M. Trost Eds., 2007, 29, 1057-1148.

(50)      P. Pornsuriyasak, M. N. Kamat, A. V. Demchenko.  Glycosyl thioimidates as versatile glycosyl donors for stereoselective glycosylation and convergent oligosaccharide synthesis.  ACS Symp. Ser.  2007, 960, 165-189.

(49)      A. F. G. Bongat, M. N. Kamat, A. V. Demchenko.  Chemoselective synthesis of oligosaccharides of 2-deoxy-2-aminosugars.  J. Org. Chem.  2007, 72, 1480-1483. (AHA-2, R15-1)

(48)      A. F. G. Bongat, A. V. Demchenko.  Recent trends in the synthesis of O-glycosides of 2-amino-deoxysugars.  Carbohydr. Res.  2007, 342, 374-406 (Special issue). (AHA-1)

(56)      M. N. Kamat, C. De Meo, A. V. Demchenko.  S-Benzoxazolyl as a stable protecting moiety and a potent anomeric leaving group in oligosaccharide synthesis.  J. Org. Chem. 2007, 72, 6947-6955. (R15-3)

(55)      M. N. Kamat, N. P. Rath, A. V. Demchenko.  Versatile synthesis and mechanism of activation of S-benzoxazolyl glycosides.  J. Org. Chem. 2007, 72, 6938-6946. (R15-2)

(54)      A. R. Parameswar, P. Pornsuriyasak, N. A. Lubanowski, A. V. Demchenko.  Efficient stereoselective synthesis of oligosaccharides of Streptococcus pneumoniae serotypes 6A and 6B containing multiple 1,2-cis glycosidic linkages. Tetrahedron, 2007, 63, 10083-10091. (PRF-4, NSF-3) 

(53)      O. V. Shulga, K. Jefferson, A. R. Khan, V. T. D’Souza, J. Liu, A. V. Demchenko, K. J. Stine.  Preparation and characterization of porous gold and its application as a platform for immobilization of acetylcholine esterase. Chem. Mater. 2007, 19, 3902-3911. (R21-1)

(52)^    C. De Meo, G. J. Boons, A. V. Demchenko.  Synthesis of glycosides of sialic acid: chemical aspects (scope and limitations).  In Comprehensive Glycoscience – From Chemistry to Systems Biology.  J. P. Kamerling Ed., Elsevier, 2007, published July 2007

(51)^    A. V. Demchenko, C. De Meo.  Product class 16: glycosyl oxygen compounds (di- and oligosaccharides). In Science of Synthesis, Houben-Weyl Methods of Molecular Transformations, D. Bellus, E. N. Jacobsen, S. V. Ley, R. Noyori, M. Regitz, P. J. Reider, E. Schaumann, I. Shinkai, E. J. Thomas and B. M. Trost Eds., 2007, 29, 1057-1148.

(50)      P. Pornsuriyasak, M. N. Kamat, A. V. Demchenko.  Glycosyl thioimidates as versatile glycosyl donors for stereoselective glycosylation and convergent oligosaccharide synthesis.  ACS Symp. Ser.  2007, 960, 165-189.

(49)      A. F. G. Bongat, M. N. Kamat, A. V. Demchenko.  Chemoselective synthesis of oligosaccharides of 2-deoxy-2-aminosugars.  J. Org. Chem.  2007, 72, 1480-1483. (AHA-2, R15-1)

(48)      A. F. G. Bongat, A. V. Demchenko.  Recent trends in the synthesis of O-glycosides of 2-amino-deoxysugars.  Carbohydr. Res.  2007, 342, 374-406 (Special issue). (AHA-1)

47)       P. Pornsuriyasak, A. V. Demchenko.  S-Thiazolinyl (STaz) glycosides as versatile building blocks for convergent selective, chemoselective, and orthogonal oligosaccharide synthesis.  Chem. Eur. J., 2006, 12, 6630-6646. (PRF-3, NSF-2)

(46)      P. Pornsuriyasak, A. V. Demchenko.  Synthesis of cancer-associated glycoantigens: stage-specific embryonic antigen 3 (SSEA-3).  Carbohydr. Res. 2006, 341, 1458-1466 (Special issue). (PRF-2, NSF-1)

(45)      A. V. Demchenko, P. Pornsuriyasak, C. De Meo.  Acetal protecting groups in the organic laboratory: synthesis of methyl 4,6-O-benzylidene-a-D-glucopyranoside.  J. Chem. Educ., 2006, 83, 782-784

(44)      J. T. Smoot, P. Pornsuriyasak, and A. V. Demchenko. Development of an arming participating group for stereoselective glycosylation and chemoselective oligosaccharide synthesis.  Angew. Chem. Int. Ed., 2005, 44, 7123-7126; Angew. Chem., 2005, 117, 7285-7288. (PRF-1)

(43)      A. V. Demchenko.  Strategic approach to the chemical synthesis of oligosaccharides.  Lett. Org. Chem., 2005, 2, 580-589.

(42)^📖    A. V. Demchenko.  Silver oxide. First update.  In Reagents for Glycoside, Nucleotide, and Peptide Synthesis, D. Crich Ed., John Wiley & Sons, Ltd, 2005, 555-556

(41)^📖    A. V. Demchenko.  Iodonium di-sym-collidine perchlorate. First update.  In Reagents for Glycoside, Nucleotide, and Peptide Synthesis, D. Crich Ed., John Wiley & Sons, Ltd, 2005, 393-394

(40)      A. Ramakrishnan, P. Pornsuriyasak, A. V. Demchenko.  Synthesis, glycosidation, and hydrolytic stability of novel glycosyl thioimidates.  J. Carbohydr. Chem., 2005, 24, 649-663 (Special issue)

(39)      M. N. Kamat, A. V. Demchenko. Revisiting the armed-disarmed concept rationale: chemoselective activation of the S-benzoxazolyl glycosides in oligosaccharide synthesis. Org. Lett., 2005, 7, 3215-3218

(38)      C. De Meo, M. N. Kamat, A. V. Demchenko.  Remote participation-assisted synthesis of b-mannosides.  Eur. J. Org. Chem., 2005, 706-711.

(37)      P. Pornsuriyasak, A. V. Demchenko.  Glycosyl thioimidates in a highly convergent one-pot strategy for oligosaccharide synthesis.  Tetrahedron: Asymmetry, 2005, 16, 433-439 (Special issue)

(36)      A. V. Demchenko.  Book review: Best synthetic methods: carbohydrates, Edited by Helen M. I. Osborn (University of Reading), Series Editor Laurence M. Harwood (University of Reading), Academic Press, An Imprint of Elsevier Science Ltd: Amsterdam–Boston–London–New York–Oxford–Paris–San Diego–San Francisco–Sydney–Tokyo, 2003. ISBN 0-12-312085-3; 430 pp.; EUR 145; US$ 145.  Carbohydr. Res., 2005, 340, 173-174

(35)      P. Pornsuriyasak, U. B. Gangadharmath, N. P. Rath, A. V. Demchenko.  A novel strategy for oligosaccharide synthesis via temporarily deactivated S-thiazolyl glycosides as glycosyl acceptors.  Org. Lett., 2004, 6, 4515-4518

(34)      U. B. Gangadharmath, A. V. Demchenko.  Nickel(II) chloride – mediated regioselective benzylation and benzoylation of diequatorial vicinal diols.  Synlett, 2004, 2191-2193

(33)      A. V. Demchenko, P. Pornsuriyasak, C. De Meo, N. N. Malysheva.  Potent, versatile, and stable: thiazolyl thioglycosides as glycosyl donors.  Angew. Chem. Int. Ed., 2004, 43, 3069-3072; Angew. Chem., 2004, 116, 3131-3134 (Editors’ Choice “Hot paper”, May 2004)

(32)^📖    A. V. Demchenko.  Silver(I) oxide, 20667-12-3 update.  In Encyclopedia of Reagents for Organic Synthesis, L. Paquette, P. Fuchs, D. Crich, and P. Wipf Eds., John Wiley & Sons, Ltd, 2004, (DOI: 10.1002/047084289 X.rs024)

(31)^    A. V. Demchenko.  Iodonium di-sym-collidine perchlorate, 69417-67-0 update.  In Encyclopedia of Reagents for Organic Synthesis, L. Paquette, P. Fuchs, D. Crich, and P. Wipf Eds., John Wiley & Sons, Ltd, 2004, (DOI: 10.1002/047084289X.ri033m)

(30)     A. V. Demchenko, M. N. Kamat, C. De Meo.  S-Benzoxazolyl (SBox) glycosides in oligosaccharide synthesis: novel glycosylation approach to the synthesis of β-D-glucosides, β-D-galactosides, and ɑ-D-mannosides.  Synlett, 2003, 1287-1290

(29)     A. V. Demchenko.  Stereoselective chemical 1,2-cis O-glycosylation: from “Sugar Ray” to modern techniques of the 21st century.  Synlett, 2003, 1225-1240 (Featured on the cover of the special issue)

(28)     A. V. Demchenko, M. A. Wolfert, B. Santhanam, J. N. Moore, G. J. Boons.  Synthesis and biological evaluation of Rhizobium sin-1 Lipid A derivatives.  J. Am. Chem. Soc., 2003, 125, 6103-6112.

(27) ^📖  G.-J. Boons, A. V. Demchenko.  The chemistry of sialic acid. In Carbohydrate-Based Drug Discovery, C.-H. Wong Ed., Wiley-VCH, Weinheim, 2003, 55-102.

(26)     A. V. Demchenko, N. N. Malysheva, C. De Meo.  S-Benzoxazolyl (SBox) glycosides as novel, versatile glycosyl donors for stereoselective 1,2-cis glycosylation.  Org. Lett., 2003, 5, 455-458.

(25)     A. V. Demchenko.  1,2-cis O-Glycosylation: methods, strategies, principles.  Curr. Org. Chem., 2003, 7, 35-79.

(24)     A. V. Demchenko, C. De Meo.  semi-Orthogonality of O-pentenyl and S-ethyl glycosides: application for the oligosaccharide synthesis.  Tetrahedron Lett., 2002, 43, 8819-8822.

(23)     C. De Meo, A. V. Demchenko, G.-J. Boons.  Trifluoroacetamido substituted sialyl donors for the preparation of sialyl galactosides. Aust. J. Chem., 2002, 55, 131-134.

(22)     C. De Meo, A. V. Demchenko, G.-J. Boons.  A stereoselective approach for the synthesis of ɑ-sialosides.  J. Org. Chem., 2001, 66, 5490-5497.

(21)     A. V. Demchenko, G.-J. Boons.  A highly convergent synthesis of a complex oligosaccharide derived from the oligosaccharide of Group B Type III Streptococcus.  J. Org. Chem., 2001, 66, 2547-2554.

(20)     G.-J. Boons, A. V. Demchenko.  Recent advances in O-sialylation.  Chem. Rev., 2000, 100, 4539-4565.

(19)     A. V. Demchenko, E. Rousson, G.-J. Boons.  Stereoselective 1,2-cis galactosylation assisted by remote neighboring group participation and solvent effects. Tetrahedron Lett., 1999, 40, 6523-6526.

(18)     A. V. Demchenko, G.-J. Boons.  A novel direct glycosylation approach for the synthesis of dimers of N-acetylneuraminic acid.  Chem. Eur. J., 1999, 5, 1278-1283.

(17)     A. V. Demchenko, G.-J. Boons.  A novel and versatile glycosyl donor for the preparation of glycosides of N-acetylneuraminic acid. Tetrahedron Lett., 1998, 39, 3065-3068.

(16)     A. Demchenko, T. Stauch, G.-J. Boons.  Solvent and other effects on the stereoselectivity of thioglycoside glycosidations. Synlett, 1997, 818-820.

(15)     A. Demchenko, G.-J. Boons.  A highly convergent synthesis of a hexasaccharide derived from the oligosaccharide of Group B Type III Streptococcus. Tetrahedron Lett., 1997, 38, 1629-1632.

(14)     A. V. Demchenko, N. N. Malysheva, N. K. Kochetkov.  Influence of experimental conditions on trityl-thiocyanate condensation reaction. Doklady Akademii Nauk, 1995, 341, 635-637.

(13)     E. M. Klimov, A. V. Demchenko, N. N. Malysheva.  Reaction of 2-deoxy-a-D-arabino-hexopyranosyl bromides with potassium thiocyanate. Doklady Akademii Nauk, 1993, 331, 53-55.

(12)     N. K. Kochetkov, E. M. Klimov, N. N. Malysheva, A. V. Demchenko.  Stereospecific synthesis of 1,2-cis glycosides of 2-amino sugars. Carbohydr. Res., 1993, 242, C7-C10.

(11)     E. M. Klimov, N. N. Malysheva, A. V. Demchenko, N. K. Kochetkov.  Synthesis of 1,2-cis-glycoside-linked regular heteropolysaccharides. Rhamnoglucan.  Doklady Akademii Nauk, 1993, 330, 330-332.

(10)     E. M. Klimov, N. N. Malysheva, A. V. Demchenko, N. K. Kochetkov.  Stereospecific synthesis of 1,2-cis glycosides of 2-aminosugars. Doklady Akademii Nauk, 1992, 325, 297-301.

(9)        N. K. Kochetkov, E. M. Klimov, N. N. Malysheva, A. V. Demchenko.  Stereospecific 1,2-cis glycosylation: a modified thiocyanate method. Carbohydr. Res., 1992, 232, C1-C5.

(8)        N. K. Kochetkov, N. N. Malysheva, E. M. Klimov, A. V. Demchenko.  Synthesis of polysaccharides with 1,2-cis-glycosidic linkages by trityl-thiocyanate polycondensation. Stereoregular a-(1->6)-D-glucan. Tetrahedron Lett., 1992, 33, 381-384.

(7)        N. K. Kochetkov, E. M. Klimov, N. N. Malysheva, A. V. Demchenko.  New modification of stereospecific 1,2-cis-glycosylation by thiocyanate method. Doklady Akademii Nauk SSSR, 1991, 321, 1203-1207.

(6)        N. K. Kochetkov, N. N. Malysheva, E. M. Klimov, A. V. Demchenko.  Synthesis of 1,2-cis-linked polysaccharides via trityl-thiocyanate condensation. Doklady Akademii Nauk SSSR, 1991, 320, 634-637.

(5)        E. M. Klimov, A. V. Demchenko, N. N. Malysheva, N. K. Kochetkov.  The synthesis of -mannosides by glycosidation of a-mannosyl thiocyanates. Bioorg. Khim., 1991, 17, 1660-1664.

(4)        N. K. Kochetkov, N. N. Malysheva, A. V. Demchenko, N. G. Kolotyrkina, E. M. Klimov.  Synthesis of 1,2-trans glycosyl thiocyanates from 1,2-anhydro sugars. Bioorg. Khim., 1991, 17, 1655-1659.

(3)        N. K. Kochetkov, E. M. Klimov, N. N. Malysheva, A. V. Demchenko.  A new stereospecific method for 1,2-cis glycosylation. Carbohydr. Res., 1991, 212, 77-91.

(2)        N. K. Kochetkov, E. M. Klimov, N. N. Malysheva, A. V. Demchenko.  A novel highly stereospecific method of 1,2-cis-glycosylation. Synthesis of -D-glucosyl- and -D-galactosyl-D-hexoses. Bioorg. Khim., 1990, 16, 701-710.

(1)        E. M. Klimov, N. N. Malysheva, A. V. Demchenko, Z. G. Makarova, V. M. Zhoulin, N. K. Kochetkov.  Effect of high pressure on the stereochemistry of glycosylation of sugars by 1,2-trans-acetates. Synthesis of gentiooligosaccharides. Doklady Akademii Nauk SSSR, 1989, 309, 110-114.